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An unusual axial–axial combination of alternating cyclic rings in the chair conformations of hexameric water and chlorine-water clusters

Naiya, S., Biswas, S., Drew, M. G. B. and Ghosh, A. (2012) An unusual axial–axial combination of alternating cyclic rings in the chair conformations of hexameric water and chlorine-water clusters. Inorganic Chemistry Communications, 20. pp. 286-289. ISSN 1387-7003

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To link to this item DOI: 10.1016/j.inoche.2012.03.030

Abstract/Summary

An alternating hexameric water (H2O)(6) cluster and a chlorine-water cluster [Cl-2(H2O)(4)](2-) in the chair forms combine axially to each other to form a 1D chain [{Cl-2(H2O)(6)}(2-)](n) in complex [FeL2]Cl center dot(H2O)(3) (L=2-[(2-methylaminoethylimino)-methyl]-phenol)]. The water molecules display extensive H-bonding interactions with monomeric iron-organic units to form a hydrogen-bonded 2D supramolecular assembly.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:30367
Uncontrolled Keywords:Hydrogen-bonded; Chlorine-water cluster; Chair conformation; X-ray diffraction analysis; Decahydronaphthalene
Publisher:Elsevier

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