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Synthesis and characterization of inorganic-organic hybrid gallium selenides

Ewing, S. J. and Vaqueiro, P. (2014) Synthesis and characterization of inorganic-organic hybrid gallium selenides. Inorganic Chemistry, 53 (17). pp. 8845-8847. ISSN 1520-510X

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To link to this item DOI: 10.1021/ic5011314

Abstract/Summary

Two semiconducting hybrid gallium selenides, [Ga6Se9(C6H14N2)4][H2O] (1) and [C6H14N2][Ga4Se6(C6H14N2)2] (2), were prepared using a solvothermal method in the pres-ence of 1,2-diaminocyclohexane (1,2-DACH). Both materials consist of neutral inorganic layers, in which 1,2-DACH is co-valently bonded to gallium. In (1), the organic amine acts as a monodentate and a bidentate ligand, while in (2) bidentate and uncoordinated 1,2-DACH molecules coexist.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:37393
Additional Information:Manuscript accepted, but not yet published online
Publisher:American Chemical Society

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