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Efficient masking of corrosion and fission products such as Ni(II) and Pd(II) in the presence of the minor actinide Am(III) using hydrophilic anionic or cationic bis-triazines

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Lewis, F. W., Harwood, L. H. ORCID: https://orcid.org/0000-0002-8442-7380, Hudson, M. J., Müllich, U. and Geist, A. (2015) Efficient masking of corrosion and fission products such as Ni(II) and Pd(II) in the presence of the minor actinide Am(III) using hydrophilic anionic or cationic bis-triazines. Chemical Communications, 51 (44). pp. 9189-9192. ISSN 1359-7345

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To link to this item DOI: 10.1039/c5cc02336j

Abstract/Summary

Water soluble anionic and cationic bis-triazine ligands are able to suppress (mask) the extraction of corrosion and fission products such as Ni(II) and Pd(II) that are found in PUREX raffinates. Thus it is possible to separate these elements from the minor actinide Am(III). Although some masking agents have previously been developed that retard the extraction of Pd(II), this is the first time a masking agent has been developed for Ni(II).

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF)
Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:40344
Publisher:The Royal Society of Chemistry
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