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The two-dimensional anharmonic oscillator II: the microwave spectrum of silyl isocyanate, SiH3NCO

Duckett, J. A., Robiette, A. G. and Mills, I. (1976) The two-dimensional anharmonic oscillator II: the microwave spectrum of silyl isocyanate, SiH3NCO. Journal of Molecular Spectroscopy, 62 (1). pp. 34-52. ISSN 0022-2852

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To link to this item DOI: 10.1016/0022-2852(76)90260-5

Abstract/Summary

The J + 1 ← J transitions (J = 2, 3, 4, 5, and 6) in the microwave spectrum of SiH3NCO have been assigned for the vibrational ground state and for the vibrational states v10 = 1, 2, and 3. The results for v10 = 0 confirm earlier work. The vibration-rotation constants show a remarkable variation with v10 and l10. To a large extent the anomalous behavior of these constants has been explained in terms of a strongly anharmonic potential function for the ν10 vibrational mode.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:7344
Publisher:Academic Press

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