Vibration-rotation spectra of monofluoroacetylene: 1700 to 7500 cm−1
Holland, J. K., Newnham, D. A., Mills, I. and Herman, M. (1992) Vibration-rotation spectra of monofluoroacetylene: 1700 to 7500 cm−1. Journal of Molecular Spectroscopy, 151 (2). pp. 346-368. ISSN 0022-2852
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To link to this article DOI: 10.1016/0022-2852(92)90571-5
High-resolution vibration-rotation spectra of monofluoroacetylene are reported for many bands in the region 1700 to 7500 cm−1. The spectra were observed on Nicolet 7199 and Bruker IFS 120 Fourier spectrometers, with resolutions of about 0.06 and 0.003 cm−1, respectively. About 130 bands have been observed in this region, of which about 80 have been rotationally analyzed. The assignment of vibrational labels to the higher energy levels is complicated by the effects of strong Fermi resonances, and many weak localized rotational resonances are observed.