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Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR

Shee, N. K., Drew, M. G. B. and Datta, D. (2017) Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR. New Journal of Chemistry, 41 (2). pp. 452-456. ISSN 1144-0546

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To link to this item DOI: 10.1039/c6nj02874h

Abstract/Summary

Using 5,6-dihydro-5,6-epoxy-1,10-phenanthroline as the ligand L, the X-ray crystal structure of [FeL3](ClO4)2·2H2O is determined. Its EPR and magnetic properties indicate entrapment of an MLCT state of the type Fe(III)–L−˙.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:74304
Uncontrolled Keywords:Materials Chemistry, General Chemistry, Catalysis
Publisher:Royal Society of Chemistry

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