Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPRShee, N. K., Drew, M. G. B. and Datta, D. (2017) Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR. New Journal of Chemistry, 41 (2). pp. 452-456. ISSN 1144-0546 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1039/c6nj02874h Abstract/SummaryUsing 5,6-dihydro-5,6-epoxy-1,10-phenanthroline as the ligand L, the X-ray crystal structure of [FeL3](ClO4)2·2H2O is determined. Its EPR and magnetic properties indicate entrapment of an MLCT state of the type Fe(III)–L−˙.
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