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Anharmonicity and local mode effects in the vibrational spectrum of NiCO4 and Co(CO)3NO

Mills, I. (1987) Anharmonicity and local mode effects in the vibrational spectrum of NiCO4 and Co(CO)3NO. Journal of Molecular Physics, 61 (3). pp. 711-724. ISSN 0026-8976

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To link to this article DOI: 10.1080/00268978700101411

Abstract/Summary

Previously published data on the vibrational fundamentals and overtones of the carbonyl stretching modes of Ni(CO)4 and Co(CO)3NO are reinterpreted using the recent model of Mills and Robiette, including Darling-Dennison resonances and local mode effects. The harmonic wavenumber θm and anharmonicity constant xm associated with the carbonyl and nitrosyl stretching modes are derived, and the 13C and 18O isotopic shifts are discussed in relation to the harmonic and anharmonic force field.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:7459
Publisher:Taylor and Francis

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