The infrared spectrum, equilibrium structure and harmonic and anharmonic force field of thioborine, HBSTurner, P. H. and Mills, I. (1982) The infrared spectrum, equilibrium structure and harmonic and anharmonic force field of thioborine, HBS. Molecular Physics, 46 (1). pp. 161-170. ISSN 1362-3028 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1080/00268978200101151 Abstract/SummaryInfrared spectra of the two stretching fundamentals of both HBS and DBS have been observed, using a continuous flow system through a multiple reflection long path cell at a pressure around 1 Torr and a Nicolet Fourier Transform spectrometer with a resolution of about 0•1 cm-1. The v3 BS stretching fundamental of DBS, near 1140 cm-1, is observed in strong Fermi resonance with the overtone of the bend 2v2. The bending fundamental v2 has not been observed and must be a very weak band. The analysis of the results in conjunction with earlier work gives the equilibrium structure (re(BH) = 1•1698(12) , re(BS) = 1•5978(3) ) and the harmonic and anharmonic force field.
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