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Signs of l-doubling constants in NF3

Stone, J. M. R. and Mills, I. (1970) Signs of l-doubling constants in NF3. Journal of Molecular Spectroscopy, 35 (3). pp. 354-358. ISSN 0022-2852

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To link to this item DOI: 10.1016/0022-2852(70)90178-5


Computed infrared band contours are presented for the two degenerate fundamentals of the NF3 molecule, using the l-resonance band contour program described by Cartwright and Mills, with values of the vibration-rotation constants determined from the microwave spectrum by Morino and co-workers. Computed contours are presented for both possible signs of the l-doubling constant, and comparison with the observed band contours leads to the conclusion that q3 = −121.4 MHz and q4 = +51.4 MHz.

Item Type:Article
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:7566
Publisher:Academic Press

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