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The vibrational spectra of natural and perdeuterated monochlorogallane, H2Ga([mu]-Cl)2GaH2, and an empirical harmonic potential function

Pulham, C. R., Downs, A. J., Goode, M. J. and Mills, I. (1995) The vibrational spectra of natural and perdeuterated monochlorogallane, H2Ga([mu]-Cl)2GaH2, and an empirical harmonic potential function. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 51 (5). pp. 769-777. ISSN 1386-1425

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To link to this item DOI: 10.1016/0584-8539(94)01288-R

Abstract/Summary

The infrared and Raman spectra of monochlorogallane and its fully deuterated isotopomer are recorded and assigned on the basis of the dimeric structures. H2Ga(μ-Cl)2GaH2 and D2Ga(μ-Cl)2GaD2, conforming to D2 symmetry. The observed frequencies are corrected for anharmonicity and fitted to a potential function in which 19 of the 33 independent force constants are refined.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:7580
Publisher:Elsevier

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