The vibrational spectra of natural and perdeuterated monochlorogallane, H2Ga([mu]-Cl)2GaH2, and an empirical harmonic potential functionTools  Pulham, C. R., Downs, A. J., Goode, M. J. and Mills, I. (1995) The vibrational spectra of natural and perdeuterated monochlorogallane, H2Ga([mu]-Cl)2GaH2, and an empirical harmonic potential function. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 51 (5). pp. 769-777. ISSN 1386-1425 Full text not archived in this repository. To link to this article DOI: 10.1016/0584-8539(94)01288-R Abstract/SummaryThe infrared and Raman spectra of monochlorogallane and its fully deuterated isotopomer are recorded and assigned on the basis of the dimeric structures. H2Ga(μ-Cl)2GaH2 and D2Ga(μ-Cl)2GaD2, conforming to D2 symmetry. The observed frequencies are corrected for anharmonicity and fitted to a potential function in which 19 of the 33 independent force constants are refined.
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