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Unprecedented photosensitivity of heterotrimetallic copper(ii)/sodium/mercury(ii) coordination polymer based thin film semiconductor device

Roy, S., Halder, S., Drew, M. G. B., Ray, P. P. and Chattopadhyay, S. (2018) Unprecedented photosensitivity of heterotrimetallic copper(ii)/sodium/mercury(ii) coordination polymer based thin film semiconductor device. New Journal of Chemistry, 42 (18). pp. 15295-15305. ISSN 1144-0546

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To link to this item DOI: 10.1039/c8nj02261e

Abstract/Summary

A hetero-polynuclear complex, [{CuLNa}2(μ-1,1,3-NCS)HgCl(μ-Cl)(μ-1,3-NCS)]n {H2L = N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine}, has been synthesized and characterized. The estimated optical band gap indicates that the complex belongs to the semiconductor family. The photosensitivity of the complex is also very high (∼57). This complex finds application in the fabrication of a Schottky barrier diode.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:78909
Uncontrolled Keywords:Materials Chemistry, General Chemistry, Catalysis
Publisher:Royal Society of Chemistry

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