Separation of minor actinides from lanthanides using immobilized ligand systems: the role of the counterionAfsar, A., Distler, P., Harwood, L., John, J., Babra, J. S., Selfe, Z., Cowell, J. and Westwood, J. (2019) Separation of minor actinides from lanthanides using immobilized ligand systems: the role of the counterion. Heterocycles, 99 (2). pp. 825-833. ISSN 1881-0942
It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.3987/COM-18-S(F)71 Abstract/SummaryA CyMe4-BTPhen functionalized silica gel that selectively extracts Am(III) over Eu(III) from 4 M HNO3 with a separation factor > 154 has been developed. Evidence is presented that the counterion surrounding the M(III) in the proposed 1:1 [BTPhen:M(III)] complex plays an important role in the complexation of Am(III) and Eu(III).
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