Accessibility navigation

Separation of minor actinides from lanthanides using immobilized ligand systems: the role of the counterion

Lists
Tools

Afsar, A., Distler, P., Harwood, L., John, J., Babra, J. S., Selfe, Z., Cowell, J. and Westwood, J. (2019) Separation of minor actinides from lanthanides using immobilized ligand systems: the role of the counterion. Heterocycles, 99 (2). pp. 825-833. ISSN 1881-0942

[img] Text - Accepted Version
· Restricted to Repository staff only until 27 December 2019.
412kB

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.3987/COM-18-S(F)71

Abstract/Summary

A CyMe4-BTPhen functionalized silica gel that selectively extracts Am(III) over Eu(III) from 4 M HNO3 with a separation factor > 154 has been developed. Evidence is presented that the counterion surrounding the M(III) in the proposed 1:1 [BTPhen:M(III)] complex plays an important role in the complexation of Am(III) and Eu(III).

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Mass Spectrometry (CAF)
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > NMR (CAF)
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Spectrometry (CAF)
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Electron Microscopy Laboratory (CAF)
ID Code:80779
Publisher:The Japan Institute of Heterocyclic Chemistry
Altmetric
Funded Project
Deposit Details

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation

See also