Accessibility navigation

Solid-state interconversions of coordination networks and hydrogen-bonded salts

Lists
Tools

Adams, C.J., Colquhoun, H.M., Crawford, P.C., Lusi, M. and Orpen, A.G. (2007) Solid-state interconversions of coordination networks and hydrogen-bonded salts. Angewandte Chemie-International Edition, 46 (7). pp. 1124-1128. ISSN 1433-7851

Full text not archived in this repository.

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.1002/anie.200603593

Abstract/Summary

Thermal or chemical treatment of crystalline 4,4-bipyridinium salts of [MCl4]2- (M=Co, Zn, Fe, or Pt) leads to HCl loss and formation of coordination network solids [{MCl2(4,4-bipy)}n]. For M=Co, Zn, and Fe, these solids can also be prepared by mechanochemical means. Their exposure to HCl vapor or the mechanochemical reaction of metal dichlorides with [4,4-H2bipy]Cl2 gives [4,4-H2bipy]2+ salts of [CoCl4]2-, [ZnCl4]2-, and, for the first time, [FeCl4]2-.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:10954
Uncontrolled Keywords:complex salts, coordination networks, crystal engineering, crystal, growth, materials synthesis, METAL-ORGANIC FRAMEWORK, MECHANOCHEMICAL PREPARATION, SUPRAMOLECULAR, SYNTHONS, CRYSTAL-STRUCTURES, CO-CRYSTALS, POLYMERS, SOLVENT, POLYMORPH, DESIGN, CHAINS
Altmetric
Deposit Details

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation

See also