Low-temperature synthesis of ordered graphite nanofibres using nickel(II)-exchanged zeolitesCardin, D.J., Lay, A.K. and Gilbert, A. (2005) Low-temperature synthesis of ordered graphite nanofibres using nickel(II)-exchanged zeolites. Journal of Materials Chemistry, 15 (3). pp. 403-406. ISSN 0959-9428 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1039/b409805f Abstract/SummaryOrdered graphite nanofibre formation has been observed at exceptionally low temperatures on admission of ethyne to zeolite Y, which had been exchanged with Ni(II). The samples have been characterised by TEM, carbon analysis, and electronic spectroscopy. Formation of the nanofibres requires no hydrogen, and was not observed when cation exchange was carried out at acidic pH. The observed fibres resemble herring-bone nanofibrils, growing from nickel particles, and ca. 90% have diameters in the range 35-40 nm. Similar fibres have also been grown using nickel-exchanged zeolite beta.
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