Dissociative electron attachment to dinitrogen pentoxide, N2O5Cicman, P., Buchanan, G.A., Marston, G., Gulejova, B., Skalny, J.D., Mason, N.J., Scheier, P. and Mark, T.D. (2004) Dissociative electron attachment to dinitrogen pentoxide, N2O5. Journal of Chemical Physics, 121 (20). pp. 9891-9897. ISSN 0021-9606 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1063/1.1806822 Abstract/SummaryElectron attachment was studied in gaseous dinitrogen pentoxide, N2O5, for incident electron energies between a few meV and 10 eV. No stable parent anion N2O5- was observed but several anionic fragments (NO3-, NO2-, NO-, O-, and O-2(-)) were detected using quadrupole mass spectrometry. Many of these dissociative pathways were found to be coupled and provide detailed information on the dynamics of N2O5 fragmentation. Estimates of the cross sections for production of each of the anionic fragments were made and suggest that electron attachment to N2O5 is amongst the most efficient attachment reactions recorded for nonhalogenated polyatomic systems. (C) 2004 American Institute of Physics.
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