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Oxo-rhenium(V) complexes with bidentate phosphine ligands: synthesis, crystal structure and catalytic potentiality in epoxidation of olefins using hydrogen peroxide activated bicarbonate as oxidant

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Dinda, S., Drew, M.G.B. and Bhattacharyya, R. (2009) Oxo-rhenium(V) complexes with bidentate phosphine ligands: synthesis, crystal structure and catalytic potentiality in epoxidation of olefins using hydrogen peroxide activated bicarbonate as oxidant. Catalysis Communications, 10 (5). pp. 720-724. ISSN 1566-7367

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To link to this item DOI: 10.1016/j.catcom.2008.11.028

Abstract/Summary

Two oxorhenium(V) complexes with bidentate phosphine ligands were synthesized and isolated as [ReOCl3(dppm)] 1 and [ReOCl3(dppp)] 2 [where dppm = 1,1-bis(diphenylphosphino) methane and dppp = 1.3-bis(diphenylphosphino) propanel. Complex 2 was structurally characterized. Both the complexes were used as catalysts in the epoxidation of olefins using NaHCO3 as co-catalyst and H2O2 as terminal oxidant. (c) 2008 Elsevier B.V. All rights reserved.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11198
Uncontrolled Keywords:Oxorhenium(V) complexes, Phosphine ligands, Crystal structure, Catalyst, Epoxidation, Alkene , RHENIUM(V) COMPLEXES, OXO COMPLEXES, TERMINAL OXIDANT, DIOXORHENIUM(V), COCATALYST, OXIDATION, ALKENES, ARSINE, OXIDES, IONS
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