Structural diversity in supramolecular architectures of Mn(II) through non-covalent interactionsGhosh, A.K., Ghoshal, D., Drew, M.G.B. and Chaudhuri, N.R. (2006) Structural diversity in supramolecular architectures of Mn(II) through non-covalent interactions. Indian Journal of Chemistry Section A, 45 (6). pp. 1351-1355. ISSN 0376-4710 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. Official URL: http://www.niscair.res.in/sciencecommunication/Res... Abstract/SummaryTwo mononuclear complexes of manganese(II), [Mn(OCN)(2)(phen)(2)] 1 and [Mn(NCO)(2)(bpy)(2)] 2 [1,10-phenanthroline (phen); 2,2'-bipyridine (bpy)], have been synthesized and characterized by single crystal X-ray analysis, infra-red spectroscopy and magnetic studies. The coordination structure of complex 2 is already reported. The cyanate anions are pendent in both the complexes. In 1, cyanate anion links manganese(II) through O-atom, whereas in 2 it coordinates through N-atom. The mononuclear fragments of 1 are built up to a supramolecular lamellar 3D architecture by pi-pi interactions only. On the other hand, mononuclear fragments of 2 are assembled to a 2D supramolecular brick-wall architecture by C-H-... pi interactions.
Deposit Details University Staff: Request a correction | Centaur Editors: Update this record |
Lists
Lists
