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Complexes of the uranyl ion with bis(diphenylphosphino)methane dioxide

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Kannan, S., Rajalakshmi, N., Chetty, K.V., Venugopal, V. and Drew, M.G.B. (2004) Complexes of the uranyl ion with bis(diphenylphosphino)methane dioxide. Polyhedron, 23 (9). pp. 1527-1533. ISSN 0277-5387

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To link to this item DOI: 10.1016/j.poly.2004.03.008

Abstract/Summary

Bis(diphenylphosphino)methane dioxide compounds of uranyl nitrate and uranyl bis(beta-diketonates) have been synthesized and characterized by spectroscopic and X-ray diffraction methods. Monodentate, bidentate chelate and bridging bidentate modes of coordination for this ligand have been established from the single-crystal X-ray diffraction studies of its compounds, [UO2(DBM)(2)DPPMO], [UO2(NO3)(2)DPPNO] and [{UO2(DBM)(2)}(2)DPPMO], respectively. (C) 2004 Elsevier Ltd. All rights reserved.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11383
Uncontrolled Keywords:bis(diphenylphosphino)methane dioxide, uranyl nitrate, uranyl bis(beta-diketonates), monodentate, bidentate chelate, bridging bidentate, coordination modes , MOLECULAR-STRUCTURE, COORDINATION CHEMISTRY, CRYSTAL-STRUCTURES, OXIDE LIGANDS, THORIUM NITRATE, DIPHOSPHINE, EXTRACTION, BIS-(DISUBSTITUTEDPHOSPHINYL)-ALKANES, ACTINIDE, DIARSINE
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