Temperature dependent high-resolution infrared photoabsorption cross-sections of trifluoromethyl sulphur pentafluorideKendall, P.A., Mason, N.J., Buchanan, G.A., Marston, G., Tegeder, P., Dawes, A., Eden, S., Limao-Vieira, P. and Newnham, D.A. (2003) Temperature dependent high-resolution infrared photoabsorption cross-sections of trifluoromethyl sulphur pentafluoride. Chemical Physics , 287 (1-2). pp. 137-142. ISSN 0301-0104 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1016/S0301-0104(02)00985-0 Abstract/SummaryAbsolute infrared photoabsorption cross-sections have been measured over the range 600-1500 cm(-1) for the powerful greenhouse gas SF5CF3 at high resolution (0.03 cm(-1)) and at temperatures between 203 and 298 K. Our data indicate that the integrated absorption intensity shows a weak negative dependence on temperature. It is concluded therefore that previous calculations of radiative forcings and global warming potentials based on room-temperature data are reasonable estimates for the atmosphere, but may be low by a few percent. (C) 2002 Elsevier Science B.V. All rights reserved.
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