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The Crucial Role of Polyatomic Anions in Molecular Architecture: Structural And Magnetic Versatility of Five Nickel(II) Complexes Derived from A N,N,O-Donor Schiff Base Ligand

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Mukherjee, P., Drew, M. G. B., Gomez-Garcia, C. J. and Ghosh, A. (2009) The Crucial Role of Polyatomic Anions in Molecular Architecture: Structural And Magnetic Versatility of Five Nickel(II) Complexes Derived from A N,N,O-Donor Schiff Base Ligand. Inorganic Chemistry, 48 (13). pp. 5848-5860. ISSN 0020-1669

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To link to this item DOI: 10.1021/ic9001863

Abstract/Summary

A series of five Ni(II)-complexes containing the same tridentate Schiff base but different monoanionic ligands (N-3(-), NO3-, PhCOO- and NO2-)reveals that the competitive as well as the cooperative role of the monoanions and phenoxo group in bridging the metal ions play the key role in the variation of molecular architecture.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11512
Uncontrolled Keywords:TRANSITION-METAL-COMPLEXES, CRYSTAL-STRUCTURE, DINUCLEAR NICKEL(II), COPPER(II) COMPLEXES, ORBITAL INTERACTIONS, NITRITE REDUCTASE, BRIDGED, DINUCLEAR, NI(II) COMPLEXES, NI-II, AZIDO
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