Accessibility navigation

Preparation and ring-opening reactions of N,O-bis(diphenylphosphinyl) hydroxymethylaziridine ('Di-Dpp')

Lists
Tools

Sweeney, J.B. and Cantrill, A.A. (2003) Preparation and ring-opening reactions of N,O-bis(diphenylphosphinyl) hydroxymethylaziridine ('Di-Dpp'). Tetrahedron, 59 (21). pp. 3677-3690. ISSN 0040-4020

Full text not archived in this repository.

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.1016/s0040-4020(03)00551-9

Abstract/Summary

N,O-bis(diphenylphosphinyl)-2-(hydroxymethyl)aziridine ('DiDpp', 1) is efficiently prepared from 2-aminoethane-1,3-diol: this activated aziridine undergoes two sequential reactions with copper(I)-modified Grignard reagents, yielding alpha-branched N-Dpp amines in good yield. (C) 2003 Elsevier Science Ltd. All rights reserved.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11644
Uncontrolled Keywords:aziridinemethanol, ring-opening, phosphinate, 2,3-EPOXY AMINES, REARRANGEMENT, 2-AZIRIDINEMETHANOLS, AZIRIDINES
Altmetric
Deposit Details

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation

See also