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Micelle-hosted bimetallic Pd-Ru nanoparticle for in situ catalytic hydrogenation in supercritical CO2

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Yu, K.M.K., Meric, P. and Tsang, S.C. (2005) Micelle-hosted bimetallic Pd-Ru nanoparticle for in situ catalytic hydrogenation in supercritical CO2. Catalysis Today, 114 (4). pp. 428-433. ISSN 0920-5861

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To link to this item DOI: 10.1016/j.cattod.2006.02.076

Abstract/Summary

Bimetallic Pd-Ru nanoparticles of different elemental ratios are prepared via in situ reduction of their simple salts in reverse micelles in supercritical carbon dioxide (scCO(2)). The optimised Pd:Ru (1: 1) nanoparticle shows the highest activity for hydrogenation of functionalised alkene under mild conditions, which can be easily recycled under the reaction conditions without use of organic solvent. (c) 2006 Elsevier B.V. All rights reserved.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11721
Uncontrolled Keywords:hydrogenation, micelle-hosted nanoparticle, bimetallic, supercritical, carbon dioxide, nitrile
Additional Information:Annual Meeting of the Surface-Reactivity-and-Catalysis-Group University of Aberdeen, Aberdeen, SCOTLAND 13-15 JUL 2005
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