The interplay between coordination and non-covalent interactions in three zinc coordination polymers
Halder, B., Middya, P., Frontera, A. Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1039/d5ce00505a Abstract/SummaryThe synthesis and characterization of three zinc(II) polymers, [(μ-OAc)3Zn2L1]n·0.5nH2O (1), [(μ-OAc)3Zn2L2]n (2), [(μ-OAc)3Zn2L3]n (3), using three tridentate ligands, HL1 {2-(((2-(diethylamino)ethyl)amino)methyl)phenol}, HL2 {4-chloro-2-(((3-(dimethylamino)propyl)amino)methyl)phenol} and HL3 {4-bromo-2-(((3-(dimethylamino)propyl)amino)methyl)phenol}, have been reported in this manuscript. The structures were confirmed by SC-XRD analysis. The DFT study analyzes the cooperative roles of bridging acetate co-ligands and NH⋯O hydrogen bonds. A structural survey of the Cambridge Structural Database (CSD) reveals that polymeric complexes derived from reduced bicompartmental Schiff base ligands are rare, emphasizing the unique structural features and supramolecular assembly observed in the present work.
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