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Temperature-responsive water-soluble copolymers based on 2-hydroxyethyl acrylate and butyl acrylate

Mun, G.A., Nurkeeva, Z.S., Beissegul, A.B., Dubolazov, A.V., Urkimbaeva, P.I., Park, K. and Khutoryanskiy, V.V. ORCID: (2007) Temperature-responsive water-soluble copolymers based on 2-hydroxyethyl acrylate and butyl acrylate. Macromolecular Chemistry and Physics, 208 (9). pp. 979-987. ISSN 1022-1352

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To link to this item DOI: 10.1002/macp.200600555


Amphiphilic copolymers have been synthesised by free radical copolymerisation of 2-hydroxyethyl acrylate with butyl acrylate, the reactivity ratios of which indicate practically equal reactivity. The copolymers containing less than 30 mol-% of BA were soluble in water and exhibited a LCST in aqueous solutions. It was found that the interaction between these copolymers and poly(acrylic acid) in aqueous solutions resulted in the formation of interpolymer complexes stabilised by hydrogen bonds and hydrophobic interactions. This interaction was significantly affected by solution I pH and led to modification of the temperature-responsive behaviour of the copolymers.

Item Type:Article
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Thermal Analysis (CAF)
Life Sciences > School of Chemistry, Food and Pharmacy > School of Pharmacy
ID Code:13676
Uncontrolled Keywords:amphiphilic polymers, hydrogen bonding, interpolymer complexes, lower, critical solution temperature, stimuli-responsive polymers, stimuli-sensitive polymers, synthesized, POLY(ACRYLIC ACID), INTERPOLYMER COMPLEXES, AQUEOUS-SOLUTIONS, VINYL, ETHER, CONTROLLED-RELEASE, ETHYLENE-GLYCOL, DRUG-DELIVERY, HYDROGELS, BEHAVIOR, POLY(N-ISOPROPYLACRYLAMIDE)

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