Synthesis and structural studies of a bis(carbamoyl methyl) sulfoxide complex of uranyl nitrateDeb, S. B., Kannan, S. and Drew, M. G. B. (2010) Synthesis and structural studies of a bis(carbamoyl methyl) sulfoxide complex of uranyl nitrate. Journal of Coordination Chemistry, 63 (20). pp. 3620-3623. ISSN 0095-8972 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1080/00958972.2010.517269 Abstract/SummaryA new tri-functional ligand iBu2NCOCH2SOCH2CONiBu2 was prepared and characterized. The coordination chemistry of this ligand with uranyl nitrate was studied with IR, 1H NMR, electrospray mass-spectrometry, thermogravimetry, and elemental analysis. The structure of [UO2(NO3)2(iBu2NCOCH2SOCH2CONiBu2)] was determined by single-crystal X-ray diffraction. The uranium(VI) ion is surrounded by eight oxygens in a hexagonal bipyramidal geometry. Four oxygens from two nitrates and two oxygens from the ligand form a planar hexagon. The ligand is a bidentate chelate, bonding through sulfoxo and one of the carbamoyl groups to uranyl nitrate.
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