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The synthesis of dicobalt and dinickel complexes of trimethylsilylethynyl-1, 2-dihydrofullerene; characterisation by n.m.r. and structure of the first acyclic metal fullerene derivative: molecular structure of [η2-{2-H-1-(Me3SiC ≡ C)-C60}Ni2(η-C5H5)2]

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Banim, F., Cardin, C. ORCID: https://orcid.org/0000-0002-2556-9995, Cardin, D., Pistocchi, M. and Todd, A. (1997) The synthesis of dicobalt and dinickel complexes of trimethylsilylethynyl-1, 2-dihydrofullerene; characterisation by n.m.r. and structure of the first acyclic metal fullerene derivative: molecular structure of [η2-{2-H-1-(Me3SiC ≡ C)-C60}Ni2(η-C5H5)2]. Journal of Physics and Chemistry Solids, 58 (11). pp. 1919-1923. ISSN 0022-3697

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To link to this item DOI: 10.1016/S0022-3697(97)00079-6

Abstract/Summary

The synthesis and characterisation of the complexes [η2-{2-H-1-(Me3SiC ≡ C)-C60}Co2(CO)6] (2)} and [η-2-{2-H-1-(Me3SiC ≡ C)-C60}Ni2η-C5H5)2] (3)} is reported, together with a single-crystal molecular structure for (3). This provides the first structural data for an acyclic metal derivative of [60]-fullerene.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:23763
Uncontrolled Keywords:fullerene; crystal structure; nickel; cobalt; alkyne
Publisher:Elsevier
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