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de Alvarenga, E. S., Cardin, C. 
ORCID: https://orcid.org/0000-0002-2556-9995 and Mann, J.
(1997)
An unexpected photoadduct of N-carbomethoxymethylpyrrolidine with a chiral butenolide and benzophenone: X-ray structure and synthetic utility.
Tetrahedron, 53 (4).
pp. 1457-1466.
ISSN 0040-4020
Full text not archived in this repository.
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To link to this item DOI: 10.1016/S0040-4020(96)01057-5
Abstract/Summary
The regio- and stereoselective photoinduced addition of N-carbomethoxymethylpyrrolidine to 5(S)-tert-butyldimethylsiloxymethyl-furan-2(5H)-one in the presence of benzophenone yields 3(R)-[N-(diphenylhydroxymethyl)carbo methoxymethylpyrrolidin-2′-yl]-4(S)-tert-butyldimethylsiloxymethyl)-butan-4-olides (epimeric at C-2′), and we report the X-ray structure of the major adduct together with its conversion into the 1-azabicyclo[4.3.0]-nonane ring system.
| Item Type: | Article |
|---|---|
| Refereed: | Yes |
| Divisions: | Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry |
| ID Code: | 23793 |
| Publisher: | Elsevier |
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