Synthesis, structure and reactivity of the novel tetratin species bromoheptakis(2,6-diethylphenyl)-cyclotetrastannabutaneCardin, C. J. ORCID: https://orcid.org/0000-0002-2556-9995, Cardin, D. J., Convery, M. A., Devereux, M. M. and Kelly, N. B. (1991) Synthesis, structure and reactivity of the novel tetratin species bromoheptakis(2,6-diethylphenyl)-cyclotetrastannabutane. Journal of Organometallic Chemistry, 414 (1). C9. ISSN 0022-328X Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1016/0022-328X(91)83251-X Abstract/SummaryMetallation of ArBr (Ar = 2,6-diethylphenyl) with Li powder in diethyl ether, followed by addition of stannous chloride at low temperature does not give the expected oligomeric diarylstannane but an essentially quantitative yield of the novel tetrastannabutane [{SnAr2}3SnArBr]. Some reactions of the new species are reported.
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