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Synthesis of the first-membered ring compound containing three tin atoms and one oxygen. The crystal structure of the species [O{Sn(C6H3Et2-2,6)2}3]

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Cardin, C. J. ORCID: https://orcid.org/0000-0002-2556-9995, Cardin, D. J., Convery, M. A. and Devereux, M. M. (1991) Synthesis of the first-membered ring compound containing three tin atoms and one oxygen. The crystal structure of the species [O{Sn(C6H3Et2-2,6)2}3]. Journal of Organometallic Chemistry, 411 (1-2). pp. 3-6. ISSN 0022-328X

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To link to this item DOI: 10.1016/0022-328X(91)86031-K

Abstract/Summary

Aerial oxidation of the novel homocyclic tetratin species [{SnAr2}3SnArBr] (1) [1] (Ar  C6H3Et2-2,6) affords the tritin heterocycle [O{Sn(C6H3Et2-2,6)2}3] (2), which has been crystallographically characterised; 2 is the first reported oxatristannacyclobutane, and the first heterocyclic tin species having both tintin and tinheteroatom bonds.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:23808
Publisher:Elsevier
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