Reversible thermal transition of polydiacetylene based on KTTKS collagen sequencePalladino, P., Castelletto, V., Dehsorkhi , A., Stetsenko, D. and Hamley, I. W. ORCID: https://orcid.org/0000-0002-4549-0926 (2012) Reversible thermal transition of polydiacetylene based on KTTKS collagen sequence. Chemical Communications, 48 (78). pp. 9774-9776. ISSN 1359-7345
It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1039/c2cc34665f Abstract/SummaryHere we explore the physico-chemical properties of a peptide amphiphile obtained by chemical conjugation of the collagenstimulating peptide KTTKS with 10,12-pentacosadiynoic acid which photopolymerizes as a stable and extended polydiacetylene. We investigate the self-assembly of this new polymer and rationalize its peculiar behavior in terms of a thermal conformational transition. Surprisingly, this polymer shows a thermal transition associated with a non-cooperative increase in b-sheet content at high temperature.
Download Statistics DownloadsDownloads per month over past year Altmetric Deposit Details University Staff: Request a correction | Centaur Editors: Update this record |