Development of molecular anisotropy in centrifugally spun fibers as compared to electrospun fibersMohan, S. D., Mitchell, G. R. and Davis, F. J. ORCID: https://orcid.org/0000-0003-0462-872X (2016) Development of molecular anisotropy in centrifugally spun fibers as compared to electrospun fibers. Macromolecular Materials and Engineering, 31 (11). pp. 1313-1319. ISSN 1439-2054 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1002/mame.201600275 Abstract/SummaryThe molecular anisotropy that is developed in microscale, centrifugally spun atactic-polystyrene fibers prepared from the solution state is examined and comparisons are made to electrospun fibers. Utilizing small angle neutron scattering, a ratio of the radius of gyration parallel to-/perpendicular to- the fiber axis is measured and a model of chain anisotropy development in the centrifugal spinning process is described.
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