Synthesis of novel BTPhen-functionalized silica-coated magnetic nanoparticles for separating trivalent actinides and lanthanides
Afsar, A., Cowell, J., Distler, P., Harwood, L. M.
It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1055/s-0036-1590865 Abstract/SummaryBTPhen [bis-(1,2,4-triazin-3-yl)-1,10-phenanthroline] functionalized magnetic nanoparticles (MNPs), which selectively extracts Am(III) over Eu(III) from 0.1 M HNO3 with fast kinetics and a separation factor of 30 have been synthesized. These MNPs also show a small but significant selectivity for Am(III) over Cm(III) with a separation factor of around 3 in 0.1 M HNO3. We report also the synthesis of these BTPhen and related ligands via an improved synthetic route by-passing the problematic benzylic oxidation with stoichiometric SeO2. Download Statistics DownloadsDownloads per month over past year Altmetric Funded Project Deposit Details University Staff: Request a correction | Centaur Editors: Update this record |
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