Abstract/Summary

The relationship between springtime mid-latitude cyclones and background ozone (O3) is explored using a combination of observational and reanalysis data sets. First, the relationship between surface O3 observations at two rural monitoring sites on the west coast of Europe – Mace Head, Ireland and Monte Velho, Portugal – and cyclone track frequency in the surrounding regions is examined. Second, detailed case study examination of four individual mid-latitude cyclones and the influence of the associated frontal passage on surface O3 is performed. Cyclone tracks have a greater influence on the O3 measurements at the more northern coastal European station, Mace Head, located within the main North Atlantic (NA) storm track. In particular, when cyclones track north of 53° N, there is a significant relationship with high levels of surface O3 (> 75th percentile). The further away a cyclone is from the NA storm track, the more likely it will be associated with both high and low (< 25th percentile) levels of O3 at the observation site during the cyclone's life cycle. The results of the four case studies demonstrate a) the importance of the passage of a cyclone's cold front in relation to surface O3 measurements, b) the ability of mid-latitude cyclones to bring down high levels of O3 from the stratosphere and c) that accompanying surface high pressure systems and their associated transport pathways play an important role in the temporal variability of surface O3. The main source of high O3 to these two sites is from the stratosphere, either from direct injection into the cyclone or associated with aged airstreams from decaying downstream cyclones that can become entrained and descend toward the surface within new cyclones over the NA region.