The infra-red spectra of silyl fluoride and silyl fluoride-d3Robiette, A. G., Cartwright, G. J., Hoy, A. R. and Mills, I. (1971) The infra-red spectra of silyl fluoride and silyl fluoride-d3. Molecular Physics, 20 (3). pp. 541-553. ISSN 1362-3028 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1080/00268977100100501 Abstract/SummaryInfra-red spectra have been recorded for silyl fluoride and silyl fluoride-d3 at a resolution of circa 0·3 cm-1. Rotational structure has been observed for parallel fundamentals in both molecules, and for all perpendicular fundamentals. In both SiH3F and SiD3F the A1 and E species deformation modes interact strongly via a Coriolis perturbation; this has been analysed, and the band origin of v5 for SiH3F is reassigned. A hybrid-orbital force field based on the experimental data is also reported.
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