The infrared spectrum of silicon difluorideCaldow, G. M., Deeley, C. M., Mills, I. and Turner, P. H. (1981) The infrared spectrum of silicon difluoride. Chemical Physics Letters, 82 (3). pp. 434-438. ISSN 0009-2614 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1016/0009-2614(81)85414-0 Abstract/SummaryThe infrared spectrum of the stretching fundamentals of SiF2 has been obtained at a resolution of ≈ 0.1 cm−1 using a FTIR spectrometer. The spectrum has been analysed using computer simulation based on a coupled hamiltonian for v1 and v3, giving v1 = 855.01 cm−1 and v3 = 870.40 cm−1. The relative magnitude and sign of the vibrational transition moments has been determined from the ξC13 Coriolis coupling.
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