Overtone bandshapes and IVR: CH stretch overtones in CHCl3Baggott, J. E., Clase, H. J. and Mills, I. (1986) Overtone bandshapes and IVR: CH stretch overtones in CHCl3. The Journal of Chemical Physics, 84. pp. 4193-4195. ISSN 0021-9606 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1063/1.450040 Abstract/SummaryThe intracavity photoacoustic dye laser spectrum of CHCl3 in the gas phase at 16 350 cm−1 is reported. The v=6–0 overtone of the CH stretch is observed, and found to exhibit a rotational band contour closely analogous to the v=1–0 fundamental. The implication of this result for intramolecular vibrational energy redistribution is discussed.
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