Preparation and characterisation of high-density ionic liquids incorporating halobismuthate anions
Cousens, N. E. A., Taylor Kearney, L. J., Clough, M. T., Lovelock, K. R. J.
It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1039/c4dt00755g Abstract/SummaryA range of ionic liquids containing dialkylimidazolium cations and halobismuthate anions ([BiBrxClyIz]− and [Bi2BrxClyIz]−) were synthesised by combining dialkylimidazolium halide ionic liquids with bismuth(III) halide salts. The majority were room temperature liquids, all with very high densities. The neat ionic liquids and their mixtures with 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide were characterised using Densitometry, Viscometry, NMR Spectroscopy, Electrospray Ionisation Mass Spectrometry (ESI), Liquid Secondary Ion Mass Spectrometry (LSIMS), Matrix-assisted Laser Desorption/Ionization Mass Spectrometry (MALDI), X-Ray Photoelectron Spectroscopy (XPS) and Thermogravimetric Analysis (TGA), to establish their speciation and suitability for high-temperature applications.
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