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Plutonium coordination and redox chemistry with the CyMe4-BTPhen polydentate N-donor extractant ligand

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Reilly, S. D., Su, J., Keith, J. M., Yang, P., Batista, E. R., Gaunt, A. J., Harwood, L. M. ORCID: https://orcid.org/0000-0002-8442-7380, Hudson, M. J., Lewis, F. W., Scott, B. L., Sharrad, C. A. and Whittaker, D. M. (2018) Plutonium coordination and redox chemistry with the CyMe4-BTPhen polydentate N-donor extractant ligand. Chemical Communications, 54 (89). pp. 12582-12585. ISSN 1359-7345

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To link to this item DOI: 10.1039/c8cc06015k

Abstract/Summary

Complexation of Pu(IV) with the actinide extractant CyMe4-BTPhen (2,9-bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-yl)-1,10-phenanthroline) was followed by vis-NIR spectroscopy in acetonitrile solution. The solid-state structure of the crystallized product suggests that Pu(IV) is reduced to Pu(III) upon complexation. Analysis by DFT modeling is consistent with metal-based rather than ligand-based reduction.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:80644
Uncontrolled Keywords:Materials Chemistry, Electronic, Optical and Magnetic Materials, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Catalysis
Publisher:The Royal Society of Chemistry
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