Article

Becerra, R., Cannady, J. P. and Walsh, R. ORCID: https://orcid.org/0000-0002-5096-6191 (2023) Time‐resolved, gas‐phase kinetic and quantum chemical studies of the reaction of germylene with hydrogen chloride. ChemPhysChem, 24 (10). e202200902. ISSN 1439-7641 doi: https://doi.org/10.1002/cphc.202200902

Al-Rubaiey, N. A. and Walsh, R. (2017) Time resolved spectroscopic investigation of SiD2 + D2: kinetic study. EPJ Web of Conferences, 139. 00004. ISSN 2100-014X doi: https://doi.org/10.1051/epjconf/201713900004

Becerra, R., Cannady, J. P., Pfrang, C. and Walsh, R. (2015) Time-resolved gas-phase kinetic, quantum chemical and RRKM studies of the reaction of silylene with 2,5-dihydrofuran. Journal of Physical Chemistry A, 119 (46). pp. 11241-11253. ISSN 1089-5639 doi: https://doi.org/10.1021/acs.jpca.5b07404

Becerra, R., Boganov, S. E., Egorov, M. P., Krylova, I. V., Promyslov, V. M. and Walsh, R. (2012) Unusual isotope effect in the reaction of chlorosilylene with trimethylsilane-1-d: Absolute rate studies and quantum chemical and Rice–Ramsperger–Kassel–Marcus calculations provide strong evidence for the involvement of an intermediate complex. Journal of the American Chemical Society, 134 (25). pp. 10493-10501. ISSN 0002-7863 doi: https://doi.org/10.1021/ja301924b

Becerra, R., Boganov, S. E., Krylova, I. V., Promyslov, V. M. and Walsh, R. (2011) A dramatic isotope effect in the reaction of ClSiH with trimethylsilane-1-d: experimental evidence for intermediate complexes in silylene Si-H(D) insertion reactions. Organometallics, 30 (16). pp. 4225-4227. ISSN 1520-6041 doi: https://doi.org/10.1021/om200411x

Becerra, R., Cannady, J. P. and Walsh, R. (2011) Time-resolved gas-phase kinetic, quantum chemical, and RRKM studies of reactions of silylene with alcohols. Journal of Physical Chemistry A, 115 (17). pp. 4231-4240. ISSN 1089-5639 doi: https://doi.org/10.1021/jp111750v

Becerra, R., Boganov, S. E., Egorov, M. P., Krylova, I. V., Nefedov, O. M., Promyslov, V. M. and Walsh, R. (2010) Gas-phase kinetics of chlorosilylene reactions II. ClSiH + C2H4: absolute rate measurements and quantum chemical and RRKM calculations for the prototype pi addition reaction. ChemPhysChem, 11 (2). pp. 419-428. ISSN 1439-7641 doi: https://doi.org/10.1002/cphc.200900490

Becerra, R., Cannady, J. P., Goulder, O. and Walsh, R. (2010) Time-resolved gas-phase kinetic, quantum chemical and RRKM studies of reactions of silylene with cyclic ethers. Journal of Physical Chemistry A, 114 (2). pp. 784-793. ISSN 1089-5639 doi: https://doi.org/10.1021/jp908289h

Becerra, R. and Walsh, R. (2010) Kinetic studies of reactions of organosilylenes: what have they taught us? Dalton Transactions, 39 (39). pp. 9217-9228. ISSN 1364-5447 doi: https://doi.org/10.1039/c0dt00198h

Becerra, R. and Walsh, R. (2010) Time-resolved gas-phase kinetic study of the germylene addition reaction, GeH2 + C2D2. Physical Chemistry Chemical Physics, 12 (12). pp. 2923-2928. ISSN 1463-9076 doi: https://doi.org/10.1039/b922506d

Becerra, R., Cannady, J. P. and Walsh, R. (2009) Direct time-resolved study of the kinetics of the reaction of silylene with phenylsilane in the gas phase. Does SiH2 react with the aromatic ring? Organometallics, 28 (21). pp. 6339-6346. ISSN 1520-6041 doi: https://doi.org/10.1021/om900712w

Becerra, R., Boganov, S. E., Egorov, M. P., Faustov, V. I., Krylova, I. V., Nefedov, O. M., Promyslov, V. M. and Walsh, R. (2009) Gas-phase kinetics of chlorosilylene reactions. I. ClSiH + Me3SiH: absolute rate measurements and theoretical calculations for prototype Si−H insertion reactions. Journal of Physical Chemistry A, 113 (19). pp. 5512-5518. ISSN 1089-5639 doi: https://doi.org/10.1021/jp901446t

Becerra, R. and Walsh, R. (2009) Time-resolved gas-phase kinetic study of the germylene addition reaction, CH3C CCH3. Physical Chemistry Chemical Physics, 11 (18). pp. 3539-3546. ISSN 1463-9076 doi: https://doi.org/10.1039/b821330e

Becerra, R., Cannady, J. P., Dormer, G. and Walsh, R. (2009) The gas-phase reaction between silylene and 2-butyne: kinetics, isotope studies, pressure dependence studies and quantum chemical calculations. Physical Chemistry Chemical Physics, 11 (26). pp. 5331-5344. ISSN 1463-9076 doi: https://doi.org/10.1039/b823109e

Becerra, R., Cannady, J. P. and Walsh, R. (2007) The reaction between silylene and ammonia: some gas-phase kinetic and quantum chemical studies. Silicon Chemistry, 3 (3-4). pp. 131-138. ISSN 1572-8994 doi: https://doi.org/10.1007/s11201-006-9018-3

Becerra, R. and Walsh, R. (2007) What have we learnt about heavy carbenes through laser flash photolysis studies? Physical Chemistry Chemical Physics, 9 (22). pp. 2817-2835. ISSN 1463-9076 doi: https://doi.org/10.1039/b617844h