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Accelerating innovations in C-H activation/functionalization through intricately designed magnetic nanomaterials: from genesis to applicability in liquid/regio/photo catalysis

Dutta, S., Kumar, P., Yadav, S., Sharma, R. D., Shivaprasad, P., Vimaleswaran, K. S., Srivastava, A. and Sharma, R. K. (2023) Accelerating innovations in C-H activation/functionalization through intricately designed magnetic nanomaterials: from genesis to applicability in liquid/regio/photo catalysis. Catalysis Communications, 175. 106615. ISSN 1566-7367

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To link to this item DOI: 10.1016/j.catcom.2023.106615

Abstract/Summary

Selective functionalization of highly inert and ubiquitous C-H bonds that would provide a ready access to synthetically valuable motifs has perplexed the chemists since long. Also, environmental benignity and economic viability have been the prime factors driving tremendous interest in C-H functionalization. This has led to many inspiring discoveries infuriating the development of potent catalytic systems that enable the facile replacement of the C-H bonds with conventional functional groups, allowing the construction of C-C, C-N, C-O, C-S, C-B and C-halogen bonds at both sp2 as well as sp3 centres. In fact, catalytic C-H functionalization strategies integrating the benefits of magnetic recovery have emerged as sustainable gateway for affording a diverse array of transformations. This review sheds light on the remarkable advancements witnessed in this area as a consequence of integrating the inherent magnetism of catalysts with the cutting-edge direct C-H functionalization strategy. Also, the promising future perspectives comprehensively covered in this review is anticipated to motivate the academic and industrial researchers, arousing their creativity for designing competent sustainable strategies to generate a plethora of pharmaceutically active molecules.

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary Research Centres (IDRCs) > Institute for Food, Nutrition and Health (IFNH)
Life Sciences > School of Chemistry, Food and Pharmacy > Department of Food and Nutritional Sciences > Human Nutrition Research Group
ID Code:109987
Publisher:Elsevier

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